全文获取类型
收费全文 | 36799篇 |
免费 | 2359篇 |
国内免费 | 1293篇 |
专业分类
电工技术 | 3051篇 |
综合类 | 2007篇 |
化学工业 | 5350篇 |
金属工艺 | 1275篇 |
机械仪表 | 3217篇 |
建筑科学 | 2697篇 |
矿业工程 | 1081篇 |
能源动力 | 10193篇 |
轻工业 | 534篇 |
水利工程 | 701篇 |
石油天然气 | 2977篇 |
武器工业 | 250篇 |
无线电 | 1041篇 |
一般工业技术 | 2621篇 |
冶金工业 | 1012篇 |
原子能技术 | 1662篇 |
自动化技术 | 782篇 |
出版年
2024年 | 63篇 |
2023年 | 578篇 |
2022年 | 962篇 |
2021年 | 1167篇 |
2020年 | 1225篇 |
2019年 | 1005篇 |
2018年 | 912篇 |
2017年 | 1004篇 |
2016年 | 1021篇 |
2015年 | 1017篇 |
2014年 | 2178篇 |
2013年 | 2391篇 |
2012年 | 2465篇 |
2011年 | 3341篇 |
2010年 | 2498篇 |
2009年 | 2325篇 |
2008年 | 2079篇 |
2007年 | 2465篇 |
2006年 | 2095篇 |
2005年 | 1670篇 |
2004年 | 1522篇 |
2003年 | 1300篇 |
2002年 | 1122篇 |
2001年 | 884篇 |
2000年 | 731篇 |
1999年 | 496篇 |
1998年 | 410篇 |
1997年 | 341篇 |
1996年 | 285篇 |
1995年 | 235篇 |
1994年 | 145篇 |
1993年 | 102篇 |
1992年 | 81篇 |
1991年 | 61篇 |
1990年 | 42篇 |
1989年 | 42篇 |
1988年 | 26篇 |
1987年 | 20篇 |
1986年 | 19篇 |
1985年 | 14篇 |
1984年 | 23篇 |
1983年 | 13篇 |
1982年 | 30篇 |
1981年 | 5篇 |
1980年 | 7篇 |
1979年 | 5篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1959年 | 12篇 |
1951年 | 11篇 |
排序方式: 共有10000条查询结果,搜索用时 234 毫秒
31.
SPEEK/cSMM membrane for simultaneous electricity generation and wastewater treatment in microbial fuel cell 下载免费PDF全文
32.
本文针对典型高温气冷堆乏燃料厂房在双发商用飞机撞击载荷下的响应及结构完整性开展研究,并探讨结构特性对撞击损伤的影响。对乏燃料厂房及飞机分别建立有限元模型,通过弹体-目标相互作用分析模拟了飞机撞击过程,综合IAEA与NRC的评价准则对乏燃料厂房在飞机撞击下的损伤程度进行评估。数值结果表明:厂房上对应于机身及发动机的撞击位置发生可接受的局部损伤;乏燃料贮存井墙体对于提高构筑物抗飞机撞击能力有重要作用。此外,构筑物外形对损伤有很大影响,圆柱形壳体的抗飞机撞击能力显著强于方形厂房,是核电厂厂房设计的优化方向之一。 相似文献
33.
《International Journal of Hydrogen Energy》2021,46(62):31778-31787
NdSrCo2O5+δ (NSCO) is a perovskite with an electrical conductivity of 1551.3 S cm−1 at 500 °C and 921.7 S cm−1 at 800 °C and has a metal-like temperature dependence. This perovskite is used as the cathode material for Ce0.8Gd0.2O2-δ (GDC)-supported microtubular solid oxide fuel cells (MT-SOFCs). The MT-SOFCs fabricated in this study consist of a bilayer anode, comprising a NiO–GDC composite layer and a NiO layer, and a NSCO–GDC composite cathode. Three cell designs with different outer tube diameters, GDC thicknesses, and NSCO/GDC ratios are designed. The MT-SOFC with an outer tube diameter of 1.86 mm, an electrolyte thickness of 180 μm, and a 5NSCO–5GDC composite cathode presents the best performance. The flexural strength of the aforementioned cell is 177 MPa, which is sufficient to confer mechanical integrity to the cell. Moreover, the ohmic and polarization resistance values of the cell are 0.22 and 0.09 Ω cm2 at 700 °C, respectively, and 0.15 and 0.03 Ω cm2 at 800 °C, respectively. These results indicate that the NSCO-GDC composite exhibits high electrochemical activity. The maximum power densities of the cell at 700 and 800 °C are 0.46 and 0.67 W cm−2, respectively, exceeding those of existing electrolyte-supported MT-SOFCs with similar electrolyte thicknesses. 相似文献
34.
《International Journal of Hydrogen Energy》2020,45(57):32856-32864
The electrode ionomer is a key factor that significantly affects the catalyst layer morphology and fuel cell performance. Herein, sulfonated poly(arylene ether sulfone)-based electrode ionomers with polymers of various molecular weights and alcohol/water mixtures were prepared, and those comprising the alcohol/water mixture showed a higher performance than the ones prepared using higher boiling solvents, such as dimethylacetamide; this is owing to the formation of the uniformly dispersed ionomer catalyst layer. The relation between ionomer molecular weight for the same polymer structure and the sulfonation degree was investigated. Because the chain length of polymer varies with molecular weight and chain entanglement degree, its molecular weight affects the electrode morphology. As the ionomer covered the catalyst, the agglomerates formed were of different morphologies according to their molecular weight, which could be deduced indirectly through dynamic light scattering and scanning electron microscopy. Additionally, the fuel cell performance was confirmed in the current-voltage curve. 相似文献
35.
36.
It is expected that demand response might provide soon ancillary services to the power system. This could be done, for example, by managing the use of Electric Vehicles (EV) batteries, or the production of flexible energy commodities such as hydrogen (H2), that can be used for fuel cell vehicles (H2EV) or in industrial processes. This paper analyses the impact of a transition to H2EV as an alternative to EV for passengers’ cars on a Spanish-like power sector. A simple H2 demand estimation is developed and provided to CEVESA, an operation and expansion model for the Iberian Power System Electricity Market (MIBEL). For this study, CEVESA was extended to include the investments and operation decisions of H2 production. Simulations were performed to determine the optimal evolution of the H2 production capacity and of the electricity generation mix, considering scenarios with different shares of EV and H2EV. The impact of H2EV vs EV mobility is assessed based on the recent Spanish National Plan for Energy and Climate (NECP) as the base case scenario. Results show that, even if H2EV mobility alternative is still more costly than EV, H2 production could provide a significant flexibility to the system that should also be appraised. Indeed, H2EV mobility could become a feasible and complementary alternative to decarbonize mobility by powering H2 production with the renewable generation surplus. This, together with the on-going learning process of this technology that will decrease its production costs and increase its efficiency in the coming years, could boost, even more, the development of the H2 economy. 相似文献
37.
Enas Taha Sayed Hussain Alawadhi A.G. Olabi Aisha Jamal Menna Salah Almahdi Juiaria Khalid Mohammad Ali Abdelkareem 《International Journal of Hydrogen Energy》2021,46(8):5975-5983
Microbial fuel cell (MFC) is a promising technology for simultaneous wastewater treatment and energy harvesting. The properties of the anode material play a critical role in the performance of the MFC. In this study, graphene oxide was prepared by a modified hummer's method. A thin layer of graphene oxide was incorporated on the carbon brush using an electrophoretic technique. The deoxygenated graphene oxide formed on the surface of the carbon brush (RGO-CB) was investigated as a bio-anode in MFC operated with real wastewater. The performance of the MFC using the RGO-CB was compared with that using plain carbon brush anode (PCB). Results showed that electrophoretic deposition of graphene oxide on the surface of carbon brush significantly enhanced the performance of the MFC, where the power density increased more than 10 times (from 33 mWm?2 to 381 mWm?2). Although the COD removal was nearly similar for the two MFCs, i.e., with PCB and RGO-CB; the columbic efficiency significantly increased in the case of RGO-CB anode. The improved performance in the case of the modified electrode was related to the role of the graphene in improving the electron transfer from the microorganism to the anode surface, as confirmed from the electrochemical impedance spectroscopy measurements. 相似文献
38.
In this study, the crystal structure, thermal, oxygen transport, electrical conductivity and electrochemical properties of the perovskite NdBa0.5Sr0.5Co2O5+δ (NBSC55) are investigated. In the temperature range of 250 °C–350 °C, the weight loss upon heating was due to a partial loss of lattice oxygen and along with a reduction of Co4+ to Co3+. The tend of weight-loss slows down as temperature increased above 350 °C indicating a reduction of Co3+ to Co2+ during this stage. The oxygen migration is dominated by surface exchange process at high temperature range (650-800 °C); however, the bulk diffusion process prevails at low temperature range (500–600 °C). For long-term testing, the polarization resistance of NBSC55 increases gradually form 3.13 Ω cm2 for 2 h to 3.34 Ω cm2 for 96 h at 600 °C and an increasing-rate for polarization resistance is around 0.22% h?1. The power density of the single cell with NBSC55 cathode reached 341 mW cm?2 at 800 °C. 相似文献
39.
高温热泵可以有效回收工业余热,达到节能减排和保护环境的目的。目前,有关高温热泵技术的研究热点在于寻找一种全球变暖潜能值(GWP)低、使用性能良好的工质,以替代现有CFC-114、HFC-245fa工质。对新型环境友好型工质HFO-1234ze(Z)进行了综述,其GWP<1,临界温度高于423 K,是一种潜在的高温热泵替代工质。总结了近年来国内外学者对HFO-1234ze(Z)的合成技术、热力学性质、输运性质、传热性能等方面的研究,并分析了HFO-1234ze(Z)在高温热泵系统中应用的可行性,认为HFO-1234ze(Z)在高温热泵中具有较好的工作性能和发展前景。 相似文献
40.
Nur Lina Rashidah Mohd Rashid Abdullah Abdul Samat Abdul Azim Jais Mahendra Rao Somalu Andanastuti Muchtar Nurul Akidah Baharuddin Wan Nor Roslam Wan Isahak 《Ceramics International》2019,45(6):6605-6615
The performance of low-to-intermediate temperature (400–800?°C) solid oxide fuel cells (SOFCs) depends on the properties of electrolyte used. SOFC performance can be enhanced by replacing electrolyte materials from conventional oxide ion (O2-) conductors with proton (H+) conductors because H+ conductors have higher ionic conductivity and theoretical electrical efficiency than O2- conductors within the target temperature range. Electrolytes based on cerate and/or zirconate have been proposed as potential H+ conductors. Cerate-based electrolytes have the highest H+ conductivity, but they are chemically and thermally unstable during redox cycles, whereas zirconate-based electrolytes exhibit the opposite properties. Thus, tailoring the properties of cerate and/or zirconate electrolytes by doping with rare-earth metals has become a main concern for many researchers to further improve the ionic conductivity and stability of electrolytes. This article provides an overview on the properties of four types of cerate and/or zirconate electrolytes including cerate-based, zirconate-based, single-doped cerate–zirconate and hybrid-doped cerate–zirconate. The properties of the proton electrolytes such as ionic conductivity, chemical stability and sinterability are also systematically discussed. This review further provides a summary of the performance of SOFCs operated with cerate and/or zirconate proton conductors and the actual potential of these materials as alternative electrolytes for proton-conducting SOFC application. 相似文献